Preparation of Ferricyanic Acid Doped Aryl Amine Copolymer and Its Electrochemical Properties

Lihuan Xu; Jiaojiao Ma; Yue Sun; Pengju Guo; Bing Han; Guosheng Wang; Chang Su

doi:doi:10.11648/j.sd.20180604.18

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Preparation of Ferricyanic Acid Doped Aryl Amine Copolymer and Its Electrochemical Properties

Lihuan Xu, Jiaojiao Ma, Yue Sun, Pengju Guo, Bing Han, Guosheng Wang, Chang Su

Published in Science Discovery (Volume 6, Issue 4)

Received: 9 August 2018 Published: 10 August 2018

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Abstract

In this paper, five hybrid copolymers of HCF/PANI，HCF/P(ANI:pPD=5:1)，HCF/P(ANI:pPD=3:1)，HCF/P(ANI:pPD=1:1)，HCF/PpPD were prepared by in-situ synthesis using the prepared ferricyanic acid (HCF) as doping acid with electrochemical activity. The prepared hybrid material was further applied as cathode electrode to prepare lithium battery. And the structure, morphology, electrochemistry and battery performance of the prepared material were studied in detail. FTIR spectra show that hybrid materials have been successfully prepared. SEM results showed that with the increase of p-phenylenediamine monomer in aromatic amine copolymer, the morphology of hybrid materials gradually decreased from the granular morphology of HCF/PANI to a relatively flat stacking state. Cyclic voltammetric (CV) test showed that the redox reaction for arylamine polymer and HCF presented two obvious characteristic peaks. And the introduction of a small amount of p-phenylenediamine monomer caused the oxidation/reduction potential of hybrid material (HCF/P(ANI:pPD=5:1)) to be significantly close each other and the peak space to decrease. With further increasing the proportion of p-phenylenediamine monomer in aromatic amine copolymer, the oxidation peak and reduction peak of hybrid material move reversely to high potential and low potential respectively. Battery performance studies showed that the initial charge-discharge specific capacities of HCF/PANI，HCF/P(ANI:pPD=5:1)，HCF/P(ANI:pPD=3:1)，HCF/P(ANI:pPD=1:1)，HCF/PpPD were 191.3 and 103.5 mAh·g^-1, 105.8 and 82.8 mAh·g^-1, 86.9 and 73.9 mAh·g^-1, 55.4 and 28.1 mAh·g^-1, 19.2 and 12.6 mAh·g^-1, respectively With the increase of p-phenylenediamine comonomers in hybrid materials, the cyclic stability of electrode materials has been improved to some extent. At the same time, the hybrid material has good rate retention.

Published in	Science Discovery (Volume 6, Issue 4)
DOI	10.11648/j.sd.20180604.18
Page(s)	276-282
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2018. Published by Science Publishing Group

Keywords

Prussian Blue, Polyphenyldiamine, Lithium Battery, Electrochemical Properties

References

[1]	P. Gómez-Romero. Hybrid organic-inorganic materials-in search of synergic activity [J]. Adv. Mater. 2001, 13(3): 163-174.
[2]	P. Gómez-Romero, G. Torres-Gómez. Molecular batteries: harnessing Fe(CN)₆^3- electroactivity in hybrid polyaniline-hexacyanoferrate electrodes [J]. Adv. Mater. 2000, 12 (19): 1454-1456.
[3]	P. Judeinstein, C. Sanchez. Hybrid organic-inorganic materials: A land of multi-disciplinarity [J]. J. Mater. Chem. 1996, 6(4): 511-525.
[4]	A. Vadivel Murugan, C. S. Gopinath, K. Vijayamohanan, Electrochemical studies of poly (3,4-ethylenedioxythiophene) PEDOT/VS2 nanocomposite as a cathode material for rechargeable lithium batteries [J]. Electrochem. Commun. 2005, 7: 213-218.
[5]	G. Li, P.G. Pickup, Phys. Ion transport in poly(3,4-ethylenedioxythiophene)-poly(styrene-4-sulfonate) composites [J]. Phys. Chem. Chem. Phys. 2000, 2: 1255-1260.
[6]	K. S. Park, S. B. Schougaard, J. B. Goodenough. Conducting-polymer/iron-redox-couple composite cathodes for lithium secondary batteries [J]. Adv. Mater. 2007, 19: 848-851.
[7]	Y. Wang, Y. Shi, L. Pan, Y. Ding, Y. Zhao, Y. Li, Y. Shi, G. Yu. Dopant-enabled supramolecular approach for controlled synthesis of nanostructured conductive polymer hydrogels [J]. Nano Lett. 2015, 15: 7736−7741.
[8]	K. A. See, S. Hug, K. Schwinghammer, M. A. Lumley, Y. Zheng, J. M. Nolt, G. D. Stucky, F. Wudl, B. V. Lotsch, R. Seshadri. Lithium charge storage mechanisms of cross-linked triazine networks and their porous carbon derivatives [J]. Chem. Mater. 2015, 27: 3821-3829.
[9]	Y. Shi, L. Peng, G. H. Yu. Nanostructured conducting polymer hydrogels for energy storage applications. Nanoscale, 2015, 7: 12796–12806.
[10]	P. Gajendran, S Vijayan, R. Saraawathi. Investigation of oxygen reduction at platinum loaded poly(o-phenylenediamine) electrode in acid medium [J]. J. Electroanal. Chem. 2007, 601(1-2): 132-138.
[11]	X. F. Lu, H. Mao, D. M. Chao. Prepatation and characterization of poly(o-phenylenediamine) microrods using ferric chloride as an oxidant [J]. Mater. Lett, 2007, 61(6): 1400-1043.
[12]	H. Yadegari, H. Heli, A. Jabbari. Graphene/poly(ortho-phenylenediamine) nanocomposite material for electrochemical supercapacitor [J]. J. Solid State Electrochem. 2013, 17: 2203–2212.
[13]	Z. H. Liu, H. H. Zhou, Z. Y. Huang, W. Y. Wang, F. Y. Zeng, Y. F. Kuang. Graphene covalently functionalized with poly(p-phenylenediamine) as high performance electrode material for supercapacitors [J]. J. Mater. Chem. A, 2013, 1, 3454-3462.
[14]	J. S. Wu, X. H. Rui, G. K. Long, W. Q. Chen, Q. Y. Yan, Q. C. Zhang. Pushing up lithium storage through nanostructured polyazaacene analogues as anode [J]. Angew. Chem. 2015, 127: 7462 –7466.
[15]	K. Gopalaiah, A. Saini, S. N. Chandrudu, D. C. Rao, H. Yadav, B. Kumar. Copper-catalyzed aerobic oxidative coupling of o-phenylenediamines with 2-aryl/heteroarylethylamines: direct access to construct quinoxalines [J]. Org. Biomol. Chem., 2017, 15: 2259–2268.
[16]	D. Asakura, M. Okubo, Y. Mizuno, T. Kudo, H. Zhou, K. Ikedo, T. Mizokawa, A. Okazawa, N. Kojima. Fabrication of a cyanide-bridged coordination polymer electrode for enhanced electrochemical ion storage ability [J]. J. Phys. Chem. C 2012, 116: 8364-8369.
[17]	L. Shen, Z. Wang, L. Chen. Prussian blues as a cathode material for lithium ion batteries [J]. Chem.- Eur. J. 2014, 20: 12559-12562.
[18]	X. J. Wang, F. Krumeich, R. Nesper. Nanocomposite of manganese ferrocyanide and graphene: A promising cathode material for rechargeable lithium ion batteries [J]. Electrochem. Commun. 2013, 34: 246-249.
[19]	M. Okubo, D. Asakura, Y. Mizuno, J.-D. Kim, T. Mizokawa, T. Kudo, I. Honma. Switching redox-active sites by valence tautomerism in prussian blue analogues AxMny[Fe(CN) ₆].nH₂O (A: K, Rb): Robust frameworks for reversible Li storage[J]. J. Phys. Chem. Lett. 2010, 1: 2063-2071.
[20]	Y. Kurihara, T. Matsuda, Y. Moritomo. Structural properties of manganese hexacyanoferrates against Li concentration[J]. Jpn. J. Appl. Phys. 2013, 52: 017301.
[21]	M. Okubo, I. Honma. Ternary metal prussian blue analogue nanoparticles as cathode materials for Li-ion batteries[J]. Dalton Trans. 2013, 42: 15881-15884.
[22]	M. Omarova, A. Koishybay, N. Yesibolati, A. Mentbayeva, N. Umirov, K. Ismailov, D. Adair, M. R. Babaa, I. Kurmanbayeva, Z. Bakenov. Nickel hexacyanoferrate nanoparticles as a low cost cathode material for lithium-ion batteries[J]. Electrochim. Acta 2015, 184: 58-63.
[23]	M. H. Wong, Z. Zhang, X. Yang, X. Chen, J. Y. Ying. One-pot in situ redox synthesisof hexacyanoferrate/ conductive polymer hybrids as lithium-ion battery cathodes[J]. Chem. Commun. 2015, 51: 13674-13677.
[24]	M. Xie, Y. X Huang, M. H. Xu, R. J. Chen, X. X. Zhang, L. Li, F. Wu. Sodium titanium hexacyanoferrate as an environmentally friendly and low-cost cathode material for sodium-ion batteries [J]. J. Power Sources 2016, 302: 7-12.
[25]	Y. Z Jiang, S. H. Yu, B. Q. Wang, Y. Li, W. P. Sun, Y. H. Lu, M. Yan, B. Song, S. X. Dou. Prussian blue@C composite as an ultrahigh-rate and long-life sodium-ion battery cathode [J]. Adv. Funct. Mater. 2016, 26: 5315–5321.
[26]	Y. You, X. Q. Yu, Y. X. Yin, K. W. Nam, Y. G. Guo. Sodium iron hexacyanoferrate with high Na content as a Na-rich cathode material for Na-ion batteries [J]. Nano. Res. 2015, 8(1): 117–128.
[27]	M. Xie, M. H. Xu, Y. X. Huang, R. J. Chen, X. X. Zhang, L. Li, F. Wu. Na2NixCo1-xFe(CN)6: A class of prussian blue analogs with transition metal elements as cathode materials for sodium ion batteries [J]. Electrochem. Commun. 2015, 59: 91–94.
[28]	J. Song, L. Wang, Y. H. Lu, J. Liu, B. K. Guo, P. H. Xiao, J. J. Lee, X. Q. Yang, G. Henkelman, J. B. Goodenough. Removal of interstitial H2O in hexacyanometallates for a superior cathode of a sodium-ion battery [J]. J. Am. Chem. Soc. 2015, 137: 2658−2664.
[29]	M. H. Wong, Z. X. Zhang, X. F. Yang, X. J. Chen, J. Y. Ying. One-pot in situ redox synthesis of hexacyanoferrate/conductive polymer hybrids as lithium-ion battery cathodes [J]. Chem. Commun., 2015, 51: 13674-13677.

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APA Style

Lihuan Xu, Jiaojiao Ma, Yue Sun, Pengju Guo, Bing Han, et al. (2018). Preparation of Ferricyanic Acid Doped Aryl Amine Copolymer and Its Electrochemical Properties. Science Discovery, 6(4), 276-282. https://doi.org/10.11648/j.sd.20180604.18

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ACS Style

Lihuan Xu; Jiaojiao Ma; Yue Sun; Pengju Guo; Bing Han, et al. Preparation of Ferricyanic Acid Doped Aryl Amine Copolymer and Its Electrochemical Properties. Sci. Discov. 2018, 6(4), 276-282. doi: 10.11648/j.sd.20180604.18

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AMA Style

Lihuan Xu, Jiaojiao Ma, Yue Sun, Pengju Guo, Bing Han, et al. Preparation of Ferricyanic Acid Doped Aryl Amine Copolymer and Its Electrochemical Properties. Sci Discov. 2018;6(4):276-282. doi: 10.11648/j.sd.20180604.18

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@article{10.11648/j.sd.20180604.18,
  author = {Lihuan Xu and Jiaojiao Ma and Yue Sun and Pengju Guo and Bing Han and Guosheng Wang and Chang Su},
  title = {Preparation of Ferricyanic Acid Doped Aryl Amine Copolymer and Its Electrochemical Properties},
  journal = {Science Discovery},
  volume = {6},
  number = {4},
  pages = {276-282},
  doi = {10.11648/j.sd.20180604.18},
  url = {https://doi.org/10.11648/j.sd.20180604.18},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sd.20180604.18},
  abstract = {In this paper, five hybrid copolymers of HCF/PANI，HCF/P(ANI:pPD=5:1)，HCF/P(ANI:pPD=3:1)，HCF/P(ANI:pPD=1:1)，HCF/PpPD were prepared by in-situ synthesis using the prepared ferricyanic acid (HCF) as doping acid with electrochemical activity. The prepared hybrid material was further applied as cathode electrode to prepare lithium battery. And the structure, morphology, electrochemistry and battery performance of the prepared material were studied in detail. FTIR spectra show that hybrid materials have been successfully prepared. SEM results showed that with the increase of p-phenylenediamine monomer in aromatic amine copolymer, the morphology of hybrid materials gradually decreased from the granular morphology of HCF/PANI to a relatively flat stacking state. Cyclic voltammetric (CV) test showed that the redox reaction for arylamine polymer and HCF presented two obvious characteristic peaks. And the introduction of a small amount of p-phenylenediamine monomer caused the oxidation/reduction potential of hybrid material (HCF/P(ANI:pPD=5:1)) to be significantly close each other and the peak space to decrease. With further increasing the proportion of p-phenylenediamine monomer in aromatic amine copolymer, the oxidation peak and reduction peak of hybrid material move reversely to high potential and low potential respectively. Battery performance studies showed that the initial charge-discharge specific capacities of HCF/PANI，HCF/P(ANI:pPD=5:1)，HCF/P(ANI:pPD=3:1)，HCF/P(ANI:pPD=1:1)，HCF/PpPD were 191.3 and 103.5 mAh·g-1, 105.8 and 82.8 mAh·g-1, 86.9 and 73.9 mAh·g-1, 55.4 and 28.1 mAh·g-1, 19.2 and 12.6 mAh·g-1, respectively With the increase of p-phenylenediamine comonomers in hybrid materials, the cyclic stability of electrode materials has been improved to some extent. At the same time, the hybrid material has good rate retention.},
 year = {2018}
}

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TY  - JOUR
T1  - Preparation of Ferricyanic Acid Doped Aryl Amine Copolymer and Its Electrochemical Properties
AU  - Lihuan Xu
AU  - Jiaojiao Ma
AU  - Yue Sun
AU  - Pengju Guo
AU  - Bing Han
AU  - Guosheng Wang
AU  - Chang Su
Y1  - 2018/08/10
PY  - 2018
N1  - https://doi.org/10.11648/j.sd.20180604.18
DO  - 10.11648/j.sd.20180604.18
T2  - Science Discovery
JF  - Science Discovery
JO  - Science Discovery
SP  - 276
EP  - 282
PB  - Science Publishing Group
SN  - 2331-0650
UR  - https://doi.org/10.11648/j.sd.20180604.18
AB  - In this paper, five hybrid copolymers of HCF/PANI，HCF/P(ANI:pPD=5:1)，HCF/P(ANI:pPD=3:1)，HCF/P(ANI:pPD=1:1)，HCF/PpPD were prepared by in-situ synthesis using the prepared ferricyanic acid (HCF) as doping acid with electrochemical activity. The prepared hybrid material was further applied as cathode electrode to prepare lithium battery. And the structure, morphology, electrochemistry and battery performance of the prepared material were studied in detail. FTIR spectra show that hybrid materials have been successfully prepared. SEM results showed that with the increase of p-phenylenediamine monomer in aromatic amine copolymer, the morphology of hybrid materials gradually decreased from the granular morphology of HCF/PANI to a relatively flat stacking state. Cyclic voltammetric (CV) test showed that the redox reaction for arylamine polymer and HCF presented two obvious characteristic peaks. And the introduction of a small amount of p-phenylenediamine monomer caused the oxidation/reduction potential of hybrid material (HCF/P(ANI:pPD=5:1)) to be significantly close each other and the peak space to decrease. With further increasing the proportion of p-phenylenediamine monomer in aromatic amine copolymer, the oxidation peak and reduction peak of hybrid material move reversely to high potential and low potential respectively. Battery performance studies showed that the initial charge-discharge specific capacities of HCF/PANI，HCF/P(ANI:pPD=5:1)，HCF/P(ANI:pPD=3:1)，HCF/P(ANI:pPD=1:1)，HCF/PpPD were 191.3 and 103.5 mAh·g-1, 105.8 and 82.8 mAh·g-1, 86.9 and 73.9 mAh·g-1, 55.4 and 28.1 mAh·g-1, 19.2 and 12.6 mAh·g-1, respectively With the increase of p-phenylenediamine comonomers in hybrid materials, the cyclic stability of electrode materials has been improved to some extent. At the same time, the hybrid material has good rate retention.
VL  - 6
IS  - 4
ER  -

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Author Information

Lihuan Xu

College of Chemical Engineering, Shenyang University of Chemical Technology, Shenyang, China
Jiaojiao Ma

College of Chemical Engineering, Shenyang University of Chemical Technology, Shenyang, China
Yue Sun

College of Chemical Engineering, Shenyang University of Chemical Technology, Shenyang, China
Pengju Guo

College of Chemical Engineering, Shenyang University of Chemical Technology, Shenyang, China
Bing Han

College of Chemical Engineering, Shenyang University of Chemical Technology, Shenyang, China
Guosheng Wang

College of Chemical Engineering, Shenyang University of Chemical Technology, Shenyang, China
Chang Su

College of Chemical Engineering, Shenyang University of Chemical Technology, Shenyang, China

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Plain Text BibTeX RIS

APA Style

Lihuan Xu, Jiaojiao Ma, Yue Sun, Pengju Guo, Bing Han, et al. (2018). Preparation of Ferricyanic Acid Doped Aryl Amine Copolymer and Its Electrochemical Properties. Science Discovery, 6(4), 276-282. https://doi.org/10.11648/j.sd.20180604.18

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ACS Style

Lihuan Xu; Jiaojiao Ma; Yue Sun; Pengju Guo; Bing Han, et al. Preparation of Ferricyanic Acid Doped Aryl Amine Copolymer and Its Electrochemical Properties. Sci. Discov. 2018, 6(4), 276-282. doi: 10.11648/j.sd.20180604.18

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AMA Style

Lihuan Xu, Jiaojiao Ma, Yue Sun, Pengju Guo, Bing Han, et al. Preparation of Ferricyanic Acid Doped Aryl Amine Copolymer and Its Electrochemical Properties. Sci Discov. 2018;6(4):276-282. doi: 10.11648/j.sd.20180604.18

Copy | Download

@article{10.11648/j.sd.20180604.18,
  author = {Lihuan Xu and Jiaojiao Ma and Yue Sun and Pengju Guo and Bing Han and Guosheng Wang and Chang Su},
  title = {Preparation of Ferricyanic Acid Doped Aryl Amine Copolymer and Its Electrochemical Properties},
  journal = {Science Discovery},
  volume = {6},
  number = {4},
  pages = {276-282},
  doi = {10.11648/j.sd.20180604.18},
  url = {https://doi.org/10.11648/j.sd.20180604.18},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sd.20180604.18},
  abstract = {In this paper, five hybrid copolymers of HCF/PANI，HCF/P(ANI:pPD=5:1)，HCF/P(ANI:pPD=3:1)，HCF/P(ANI:pPD=1:1)，HCF/PpPD were prepared by in-situ synthesis using the prepared ferricyanic acid (HCF) as doping acid with electrochemical activity. The prepared hybrid material was further applied as cathode electrode to prepare lithium battery. And the structure, morphology, electrochemistry and battery performance of the prepared material were studied in detail. FTIR spectra show that hybrid materials have been successfully prepared. SEM results showed that with the increase of p-phenylenediamine monomer in aromatic amine copolymer, the morphology of hybrid materials gradually decreased from the granular morphology of HCF/PANI to a relatively flat stacking state. Cyclic voltammetric (CV) test showed that the redox reaction for arylamine polymer and HCF presented two obvious characteristic peaks. And the introduction of a small amount of p-phenylenediamine monomer caused the oxidation/reduction potential of hybrid material (HCF/P(ANI:pPD=5:1)) to be significantly close each other and the peak space to decrease. With further increasing the proportion of p-phenylenediamine monomer in aromatic amine copolymer, the oxidation peak and reduction peak of hybrid material move reversely to high potential and low potential respectively. Battery performance studies showed that the initial charge-discharge specific capacities of HCF/PANI，HCF/P(ANI:pPD=5:1)，HCF/P(ANI:pPD=3:1)，HCF/P(ANI:pPD=1:1)，HCF/PpPD were 191.3 and 103.5 mAh·g-1, 105.8 and 82.8 mAh·g-1, 86.9 and 73.9 mAh·g-1, 55.4 and 28.1 mAh·g-1, 19.2 and 12.6 mAh·g-1, respectively With the increase of p-phenylenediamine comonomers in hybrid materials, the cyclic stability of electrode materials has been improved to some extent. At the same time, the hybrid material has good rate retention.},
 year = {2018}
}

Copy | Download

TY  - JOUR
T1  - Preparation of Ferricyanic Acid Doped Aryl Amine Copolymer and Its Electrochemical Properties
AU  - Lihuan Xu
AU  - Jiaojiao Ma
AU  - Yue Sun
AU  - Pengju Guo
AU  - Bing Han
AU  - Guosheng Wang
AU  - Chang Su
Y1  - 2018/08/10
PY  - 2018
N1  - https://doi.org/10.11648/j.sd.20180604.18
DO  - 10.11648/j.sd.20180604.18
T2  - Science Discovery
JF  - Science Discovery
JO  - Science Discovery
SP  - 276
EP  - 282
PB  - Science Publishing Group
SN  - 2331-0650
UR  - https://doi.org/10.11648/j.sd.20180604.18
AB  - In this paper, five hybrid copolymers of HCF/PANI，HCF/P(ANI:pPD=5:1)，HCF/P(ANI:pPD=3:1)，HCF/P(ANI:pPD=1:1)，HCF/PpPD were prepared by in-situ synthesis using the prepared ferricyanic acid (HCF) as doping acid with electrochemical activity. The prepared hybrid material was further applied as cathode electrode to prepare lithium battery. And the structure, morphology, electrochemistry and battery performance of the prepared material were studied in detail. FTIR spectra show that hybrid materials have been successfully prepared. SEM results showed that with the increase of p-phenylenediamine monomer in aromatic amine copolymer, the morphology of hybrid materials gradually decreased from the granular morphology of HCF/PANI to a relatively flat stacking state. Cyclic voltammetric (CV) test showed that the redox reaction for arylamine polymer and HCF presented two obvious characteristic peaks. And the introduction of a small amount of p-phenylenediamine monomer caused the oxidation/reduction potential of hybrid material (HCF/P(ANI:pPD=5:1)) to be significantly close each other and the peak space to decrease. With further increasing the proportion of p-phenylenediamine monomer in aromatic amine copolymer, the oxidation peak and reduction peak of hybrid material move reversely to high potential and low potential respectively. Battery performance studies showed that the initial charge-discharge specific capacities of HCF/PANI，HCF/P(ANI:pPD=5:1)，HCF/P(ANI:pPD=3:1)，HCF/P(ANI:pPD=1:1)，HCF/PpPD were 191.3 and 103.5 mAh·g-1, 105.8 and 82.8 mAh·g-1, 86.9 and 73.9 mAh·g-1, 55.4 and 28.1 mAh·g-1, 19.2 and 12.6 mAh·g-1, respectively With the increase of p-phenylenediamine comonomers in hybrid materials, the cyclic stability of electrode materials has been improved to some extent. At the same time, the hybrid material has good rate retention.
VL  - 6
IS  - 4
ER  -

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