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Hierarchical Microchannel Carbons Derived from Biological Phloem Tissues as High-Performance Anode for Lithium-Ion Batteries

Received: 29 June 2021     Accepted: 15 July 2021     Published: 15 September 2021
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Abstract

With the upgrading of consumption, the existing carbon-based anode materials are facing the major challenges of high preparation cost and low initial Coulomb efficiency. The fast-growing and developed sieve tube network is an inspiration to transform cattail phloem tissue (CPT) into a high-performance carbon-based anode for lithium-ion battery. In this study, porous carbon materials from CPT with abundant microchannel and nanochannel were prepared by a top-down strategy combined with an indispensable passivation process. The sidewall and end of the sieve tube are fully covered by a large number of pore structures and various supporting cells, thus ensuring the stiffness and tensile strength of phloem tissue. And benefiting from the neoteric hierarchical porous structure without Li+ trapping sites, the cells with CPT anode showed high electrochemical performance. For the passivated CPT electrode, the reversible capacity increased to 321.6 mAh/g, and the initial Coulomb efficiency was 1.47 times higher than that of the passivated CPT electrode. The CPT exhibits excellent rate performance under high current, which indicates that the abundant pore structure on the surface of the sieve tube is an effective measure to improve ion diffusion. Besides, the generation mechanism of high-performance CPT is analyzed through microstructure characterization. The improvement of electrochemical performance of CPT in this work has provided a clear strategy for the application of resource-rich natural biomass to electrochemical products.

Published in Journal of Electrical and Electronic Engineering (Volume 9, Issue 5)
DOI 10.11648/j.jeee.20210905.12
Page(s) 153-160
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2021. Published by Science Publishing Group

Keywords

Phloem Tissue Carbon, Porous Anode, Lithium-Ion Battery, Biomass Carbon

References
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    Yunlong Liao, Jiahua Hu, Zhuang Sun, Wei Zhang, Xiaomeng Zhou, et al. (2021). Hierarchical Microchannel Carbons Derived from Biological Phloem Tissues as High-Performance Anode for Lithium-Ion Batteries. Journal of Electrical and Electronic Engineering, 9(5), 153-160. https://doi.org/10.11648/j.jeee.20210905.12

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    ACS Style

    Yunlong Liao; Jiahua Hu; Zhuang Sun; Wei Zhang; Xiaomeng Zhou, et al. Hierarchical Microchannel Carbons Derived from Biological Phloem Tissues as High-Performance Anode for Lithium-Ion Batteries. J. Electr. Electron. Eng. 2021, 9(5), 153-160. doi: 10.11648/j.jeee.20210905.12

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    AMA Style

    Yunlong Liao, Jiahua Hu, Zhuang Sun, Wei Zhang, Xiaomeng Zhou, et al. Hierarchical Microchannel Carbons Derived from Biological Phloem Tissues as High-Performance Anode for Lithium-Ion Batteries. J Electr Electron Eng. 2021;9(5):153-160. doi: 10.11648/j.jeee.20210905.12

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  • @article{10.11648/j.jeee.20210905.12,
      author = {Yunlong Liao and Jiahua Hu and Zhuang Sun and Wei Zhang and Xiaomeng Zhou and Haijun Zhang},
      title = {Hierarchical Microchannel Carbons Derived from Biological Phloem Tissues as High-Performance Anode for Lithium-Ion Batteries},
      journal = {Journal of Electrical and Electronic Engineering},
      volume = {9},
      number = {5},
      pages = {153-160},
      doi = {10.11648/j.jeee.20210905.12},
      url = {https://doi.org/10.11648/j.jeee.20210905.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.jeee.20210905.12},
      abstract = {With the upgrading of consumption, the existing carbon-based anode materials are facing the major challenges of high preparation cost and low initial Coulomb efficiency. The fast-growing and developed sieve tube network is an inspiration to transform cattail phloem tissue (CPT) into a high-performance carbon-based anode for lithium-ion battery. In this study, porous carbon materials from CPT with abundant microchannel and nanochannel were prepared by a top-down strategy combined with an indispensable passivation process. The sidewall and end of the sieve tube are fully covered by a large number of pore structures and various supporting cells, thus ensuring the stiffness and tensile strength of phloem tissue. And benefiting from the neoteric hierarchical porous structure without Li+ trapping sites, the cells with CPT anode showed high electrochemical performance. For the passivated CPT electrode, the reversible capacity increased to 321.6 mAh/g, and the initial Coulomb efficiency was 1.47 times higher than that of the passivated CPT electrode. The CPT exhibits excellent rate performance under high current, which indicates that the abundant pore structure on the surface of the sieve tube is an effective measure to improve ion diffusion. Besides, the generation mechanism of high-performance CPT is analyzed through microstructure characterization. The improvement of electrochemical performance of CPT in this work has provided a clear strategy for the application of resource-rich natural biomass to electrochemical products.},
     year = {2021}
    }
    

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  • TY  - JOUR
    T1  - Hierarchical Microchannel Carbons Derived from Biological Phloem Tissues as High-Performance Anode for Lithium-Ion Batteries
    AU  - Yunlong Liao
    AU  - Jiahua Hu
    AU  - Zhuang Sun
    AU  - Wei Zhang
    AU  - Xiaomeng Zhou
    AU  - Haijun Zhang
    Y1  - 2021/09/15
    PY  - 2021
    N1  - https://doi.org/10.11648/j.jeee.20210905.12
    DO  - 10.11648/j.jeee.20210905.12
    T2  - Journal of Electrical and Electronic Engineering
    JF  - Journal of Electrical and Electronic Engineering
    JO  - Journal of Electrical and Electronic Engineering
    SP  - 153
    EP  - 160
    PB  - Science Publishing Group
    SN  - 2329-1605
    UR  - https://doi.org/10.11648/j.jeee.20210905.12
    AB  - With the upgrading of consumption, the existing carbon-based anode materials are facing the major challenges of high preparation cost and low initial Coulomb efficiency. The fast-growing and developed sieve tube network is an inspiration to transform cattail phloem tissue (CPT) into a high-performance carbon-based anode for lithium-ion battery. In this study, porous carbon materials from CPT with abundant microchannel and nanochannel were prepared by a top-down strategy combined with an indispensable passivation process. The sidewall and end of the sieve tube are fully covered by a large number of pore structures and various supporting cells, thus ensuring the stiffness and tensile strength of phloem tissue. And benefiting from the neoteric hierarchical porous structure without Li+ trapping sites, the cells with CPT anode showed high electrochemical performance. For the passivated CPT electrode, the reversible capacity increased to 321.6 mAh/g, and the initial Coulomb efficiency was 1.47 times higher than that of the passivated CPT electrode. The CPT exhibits excellent rate performance under high current, which indicates that the abundant pore structure on the surface of the sieve tube is an effective measure to improve ion diffusion. Besides, the generation mechanism of high-performance CPT is analyzed through microstructure characterization. The improvement of electrochemical performance of CPT in this work has provided a clear strategy for the application of resource-rich natural biomass to electrochemical products.
    VL  - 9
    IS  - 5
    ER  - 

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Author Information
  • School of Safety Science and Engineering, Civil Aviation University of China, Tianjin, China

  • School of Safety Science and Engineering, Civil Aviation University of China, Tianjin, China

  • The State Key Lab of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, P. R. China

  • School of Safety Science and Engineering, Civil Aviation University of China, Tianjin, China

  • Key Laboratory of Civil Aviation Thermal Hazards Prevention and Emergency Response, Civil Aviation University of China, Tianjin, China

  • Key Laboratory of Civil Aviation Thermal Hazards Prevention and Emergency Response, Civil Aviation University of China, Tianjin, China

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